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I'm guessing you're talking about Washington, DC.
Metro is a subway system that links downtown Washington, DC with the suburbs in Virginia and Maryland.
MARC is a commuter train system operated by the state of Maryland that mostly operates on weekdays, connecting parts of Maryland (in particular Baltimore) with downtown DC.
Amtrak is a US-wide train system that connects parts of the country. If you want to go from DC to New York by train, you would ride on Amtrak, which leaves from Washington Union Station.