About aqueous potassium hydroxide and the volume of solution after dissolving?

2014-09-13 2:07 pm
Concerning the following questions,

A gaseous compound X contains C, H and O only.
100cm^3 of X are mixed with 500cm^3 of oxygen which is known to be in excess. On complete combustion and after cooling back to room temperature, the resulting volume of the reaction mixture is 400 cm^3. On passing the reacting mixture through aqueous potassium hydroxide, the volume is further reduced to 200cm^3.

The answer key says the volume of CO2 produced is 200cm^3 and the volume of O2 consumed is 300cm^3.

Here are my questions:
1) Do aqueous KOH absorbs both water and CO2?

2)I supposed there are CO2, H2O and O2 in the 400cm^3 reaction mixture. Why can it be deduced that there are 200cm^3 CO2 and the 200cm^3 mixture after passing through KOH are all O2?

thanks.

回答 (1)

2014-09-13 5:05 pm
The analyzed gas sample is at Room Temperature. This means the water is a liquid (plus a small, probably insignificant, amount of humidity).
Absorbtion of CO2 shows 200ml of that component. The other 200ml of gas must be residual O2. Since you began with 500ml, you consumed the difference in the reaction.


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