問題關於量子力學和電子

2014-08-07 3:53 am
學完量子力學後
回想起幾月前所學的電子層
量子力學不是說粒子會隨機在不同的地方和向不同的方向移動的嗎?
這麼為何
1st shell有2粒
2st shell有8粒
....
感覺上電子會隨機在不同的地方的話不會這麼準確地有2粒電子在同一個電子層吧?
如果是隨機,為何電子會這麼準確分配在不同的電子層?
到底是
1st shell有2粒
2st shell有8粒
還是
1st shell最多有2粒出現
2st shell最多有8粒出現
?

回答 (1)

2014-08-07 4:42 am
✔ 最佳答案
You need to distinguish betwween electrons in the free state and electrons in the bound state. Electrons in atomic orbits are in a bound state.

In quantum mechanics, electrons belong to the class of particles called "fermions", which obey the Pauli Exclusion Principle. Briefly speaking, no two electrons (fermions) can possess the same energy (more exactly, the same quantum state). This principle governs the distribution of electrons in orbits of an atom.

In the ground state of an atom, electrons fill all lowest possible energy states (i.e. orbits). Since an electron has two spins (+ve and -ve, which indicates the direction of spin), an orbital level (termed an energy level in quantum mechanics) can only accommodate at most two electrons in order to comply with the Pauli Exclusion Principle.

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