Can somebody answer these chemistry questions?

2014-02-04 2:35 pm
1. A mixture of BaO and CaO weighing 3.50g is transformed into mixed sulfates, BaSO4 and CaSO4 weighing 5.7204g. Calculate the number of grams CaO and BaO in the mixture. What weight of limestone should be taken so that 2/3 the number of mg of CaSO4 obtained will represent the percentage of CaO in the numeral?

2. When 1.00 gram precipitated AgCl + AgBr was heated on a current of Cl2, AgBr is converted to AgCl and the mixture loses 0.1470g in weight. Find the percentage Cl in the original mixture.

回答 (1)

2014-02-05 12:19 am
✔ 最佳答案
1.
Let z be the mass in grams of BaO in the mixture.
Then 3.50 - z is the mass of CaO in the mixture.

Supposing both oxides undergo the same sort of reaction in equimolar amounts.

z / (153.3271 g BaO/mol) x ( 233.3909 g BaSO4/mol) = g BaSO4

(3.50 - z) / (56.0778 g CaO/mol) x (136.1416 g CaSO4/mol) = g CaSO4

So the sum of the last two expressions equals 5.7204 g.

Written algebraically:

(z / (153.3271) x ( 233.3909 )) + ((3.50 - z) / (56.0778 ) x (136.1416 )) = 5.7204
Solve for z:
z = 3.07 g BaO
3.50 - 3.07 = 0.43 g CaO

What "numeral"?

2.
2 AgBr + Cl2 → Br2 + 2 AgCl

The weight loss is due to the difference in molar mass between AgBr and AgCl.
(0.1470 g) / ((187.7723 g AgBr/mol) - (143.3214 g AgCl/mol)) = 0.00330702 mol AgBr converted

(0.00330702 mol AgBr) x (187.7723 g AgBr/mol) = 0.620967 g AgBr in the original answer

1.00 g total - 0.620967 g AgBr = 0.379033 g AgCl

(0.379033 g AgCl) / (143.3214 g AgCl/mol) x (1 mol Cl / 1 mol AgCl) x (35.4532 g Cl/mol) / (1.00 g) =
0.0938 = 9.38% Cl by mass


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