化學題!求解答!

2013-11-20 10:25 pm
NO +co2------------>no2+co
把4molNO和0.9molco2注入2dm3容器中。平衡時,有0.1mol co2生成,反應常數是多少,求解釋!
更新1:

但答案係2.00

回答 (2)

2013-11-20 10:50 pm
✔ 最佳答案
NO(g) + CO₂(g) <===> NO₂(g) + CO(g)

intial
no. of mole of NO = 4
no. of mole of CO₂ = 0.9
no. of mole of NO₂ = 0
no. of mole of CO = 0

At eqm.
no. of mole of NO = 4 - 0.1 = 3.9
no. of mole of CO₂ = 0.9 - 0.1 = 0.8
no. of mole of NO₂ = 0.1
no. of mole of CO = 0.1

At. eqm.

[ NO ] = 3.9/2 = 1.95 mol / dm³
[ CO₂ ] = 0.8/2 = 0.4 mol / dm³
[ NO₂ ] = 0.1/2 = 0.05 mol / dm³
[ CO ] = 0.1/2 = 0.05 mol / dm³

Kc = [ NO₂ ][ CO ] / [ NO ][ CO₂ ] = (0.05)(0.05)/(0.95)(0.4)
= 0.0066

2013-11-21 02:07:34 補充:
解錯了題目意思,題目寫為 [ 有0.1mol co2 剩餘 ] 可能好一點。

At eqm.
no. of mole of CO₂ = 0.1
no. of mole of NO = 4 - 0.8 = 3.2
no. of mole of NO₂ = 0.8
no. of mole of CO = 0.8

2013-11-21 02:09:54 補充:
At. eqm.

[ NO ] = 3.2/2 = 1.6 mol / dm³
[ CO₂ ] = 0.1/2 = 0.05 mol / dm³
[ NO₂ ] = 0.8/2 = 0.4 mol / dm³
[ CO ] = 0.8/2 = 0.4 mol / dm³

Kc = [ NO₂ ][ CO ] / [ NO ][ CO₂ ] = (0.4)(0.4)/(1.6)(0.05)
= 2
2013-11-20 11:13 pm
答案係2.00!!!!

2013-11-21 11:22:14 補充:
Thx a lot!


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