Complete neutralization ques

2013-03-30 4:10 am
3.65g of sodium carbonate was dissolved in water and made up to 250cm cube solution. 25cm cube of this solution required 20cm cube of hydrochloric acid for complete neutralization.Find the molarity of the hydrochloric acid.
急,唔該
更新1:

molarity係0.0344M wo

更新2:

可唔可以解釋下點係*(25/250),而唔係*(250/25)

更新3:

咁250/25幾時用得上,我見有兩個case

更新4:

a chemist first diluted 10.0cm3 of vinegar to 100.0cm3.Then he took 25.0cm3 of the diluted solution and titrated it against 0.105mol dm-3 sodium hydroxide solution, using phenolphthalein as an indicator.15.9cm3 of the alkali were required to reach the end point.

更新5:

And then ,calculate the molarity of the ethanoic acid in the original vinegar 呢個case你點睇

回答 (1)

2013-04-01 2:43 am
✔ 最佳答案
Molar mass of Na2CO3 = 23x2 + 12+ 16x3 = 106 g/mol
No. of moles of Na2CO3 used to make 250 cm³ solution =3.65/106 = 0.0344 mol

Out of the 250 cm³ Na2CO3­ solution, only 25 cm³ is usedin titration.
No. of moles of Na2CO3 used in titration = 0.0344 x(25/250) = 0.00344 mol

Reaction in the titration :
Na2CO3 + 2HCl → 2NaCl + H2O + CO2
No. of moles of Na2CO3 used in titration = 0.00344 mol
No. of moles of HCl used in titration = 0.00344 x 2 = 0.00688 mol
Molarity of HCl used = 0.00688 / (20/1000) = 0.344M

(The given answer 0.0344 M is INCORRECT.)

2013-04-01 04:00:55 補充:
The volume of the solution made is 250 cm³, but only 25 cm³ is used in titration.
The fraction of the solution used in titration = 25/250

所製成溶液的體積是 250 cm³,在滴定中只使用了其中的 25 cm³。
用於滴定的溶液的分率 = 25/250

2013-04-01 04:01:28 補充:
The volume of the solution made is 250 cm³, but only 25 cm³ is used in titration.
The fraction of the solution used in titration = 25/250

所製成溶液的體積是 250 cm³,在滴定中只使用了其中的 25 cm³。
用於滴定的溶液的分率 = 25/250

2013-04-02 02:28:04 補充:
你有 case 便拿出來討論吧!

2013-04-02 23:44:52 補充:
Consider the titration :
CH3COOH + NaOH → CH3COONa + H2O

No. of moles of NaOH used in titration = 0.105 x (15.9/1000) = 0.00167 mol
No. of moles of diluted CH3COOH used in titration = 0.00167 molVolume of diluted

2013-04-02 23:45:14 補充:
CH3COOH used in titration = 25 cm³ = 0.025 dm³
Molarity of diluted CH3COOH used in titration = 0.00167/(0.025) = 0.0668 M

Molarity of CH3COOH in the original solution = 0.0668 x (100/10) = 0.668 M

2013-04-02 23:46:06 補充:
Consider the titration :
CH3COOH + NaOH → CH3COONa + H2O

No. of moles of NaOH used in titration = 0.105 x (15.9/1000) = 0.00167 mol
No. of moles of diluted CH3COOH used in titration = 0.00167 mol

2013-04-02 23:46:26 補充:
Volume of diluted CH3COOH used in titration = 25 cm³ = 0.025 dm³
Molarity of diluted CH3COOH used in titration = 0.00167/(0.025) = 0.0668 M

Molarity of CH3COOH in the original solution = 0.0668 x (100/10) = 0.668 M
參考: 老爺子, 老爺子, 老爺子, 老爺子


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