07 AL IA 3(b)
A mixture of Fe3+(aq) and Cu2+(aq) is separated by paper chromatography using a mixture of propanone and 6M HCl(aq) as the mobile phase. Suggest how you would identify chemically the Fe3+(aq) and Cu2+(aq) on the chromatographic paper.
As the two ions have different colours, I thought they can be simply distinguished by their colours, i.e. a yellow brown spot will appear, representing the presence of Fe3+(aq) and a blue spot will appear, representing the presence of Cu2+(aq)
but in the marking scheme, it said
Place the chromatographic paper in an atmosphere of ammonia.
Fe3+(aq) reacts with OH-(aq) to give brown Fe(OH)3(s)
Cu2+(aq) reacts with NH3(aq) to give deep blue complex [Cu(NH3)4]2+ (aq)
why?
can the chromatographic paper in an atmosphere of sodium hydroxide solution instead? why?
plz help me:)