✔ 最佳答案
CH3OH(l) + (3/2)O2(g) → CO2(g) + 2H2O(l).. ΔH = a
CO(g) + (1/2)O2(g) → CO2(g) .. ΔH = b
2CO2(g) + 2H2O(l) →CH3COOH(l) + 2O2(g).. ΔH = -c
把以上三條熱反應式相加,並消去兩邊的 2O2(g)、2H2O(l) 和 2 CO2(g) :
CH3OH(l) + CO(g) → CH3COOH(l) .. ΔH = a + b - c
以上反應式的係數和 = 1 + 1 + 1 = 3
2013-02-16 22:58:46 補充:
計算 ΔH 的另一方法:
ΔH = ΔHc[CH3OH(l)] + ΔHc[CO(g)] - ΔHC[CH3COOH(l)] = a + b - c