✔ 最佳答案
無論左室或右室:
PV = nRT
PV/T = nR
由於 n 和 R 均為常數,故此 PV/T = 常數
P1V1/T1 = P2V2/T2
設左右兩室原來的的壓力均為 Po,原來的體積均為 Vo。
設左室加熱後兩室壓力均為 P1,左室體積為 VL,則右室體積為 2Vo - VL。
只考慮左室(L):
PL1 = Po, VL1 = Vo, TL1 = 273 + 27= 300K
PL2 = P1, VL2= VL, TL2 = 273 + 127= 400K
PL1VL1/TL1 = PL2VL2/TL2
Po x Vo / 300 = P1 x VL / 400
P1 = 4PoVo / 3VL ...... [1]
只考慮右室(R):
PR1 = Po, VR1 = Vo, TR1 = 273 + 27= 300K
PR2 = P1, VR2= 2Vo - VL, TR2 = 273 + 27 =300K
PR1VR1/TR1 = PR2VR2/TR2
Po x Vo x 300 = P1 x (2Vo - VL)x 300
P1 = PoVo / (2Vo - VL)...... [2]
[1] = [2] :
3PoVo / 4VL = PoVo / (2Vo- VL)
4 / 3VL = 1 / (2Vo - VL)
4(2Vo - VL) = 3VL
8Vo - 4VL = 3VL
7VL = 8Vo
VL = 8Vo/7
左室氣體體積的增加百分率
= [(VL - Vo)/Vo] x 100%
= [(8Vo/7 - Vo)/Vo] x 100%
= (1/7) x 100%
= 14.3%
2012-12-26 01:17:24 補充:
兩室的總體積不變,但加熱一室體積增加,另一室體積下降。