NH3 will have the highest boiling point because NH3 molecules can form hydrogen bonds with each other. The other molecules will increase in boiling point with size. So, in order of decreasing boiling point:
RE:
Rank the molecules from highest to lowest boiling point?
The hydrides of group 5A are NH3, PH3, AsH3, and SbH3. Arrange them from highest to lowest boiling point.
Boiling point is related to intermolecular forces.
NH3 is a predominantly a hydrogen bond therefore, it has the highest boiling point of these compounds.
Than it would go, AsH3 and then SbH3. AsH3 comes first because it has a smaller atomic radii, therefore making it a more compacted molecule and harder to break apart.