高中化學1題(急需)

2012-05-02 9:50 am
在0.2M氨水5.0L中,需加入若干克NH4Cl,方能使此溶液之[OH-]濃度變為1.0*10^-5M?(氨水的Kb=1.6*10^-5)

回答 (1)

2012-05-02 11:24 am
✔ 最佳答案
設加入 m 克的 NH4Cl。

[NH3]o = 0.2 M
[NH4Cl]o = [m/(14 + 1x4 + 35.5)]/5 = m/267.5 M

NH3(aq) + H2O(l) ⇌ NH4^+(aq) +OH^-(aq)
平衡時:
[NH3] = 0.2 M - (1.0 x 10^-5) ≈ 0.2 M
[NH4^+] = (m/267.5) + (1.0 x 10^-5) = m/267.5 M

Kb = [NH4^+][OH^-]/[NH3]
(m/267.5)(1.0 x 10^-5)/(0.2) = 1.6 x 10^-5
m = 85.6

所加入 NH4Cl 的質量 = 65.6 g
參考: fooks


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