✔ 最佳答案
First, just to remove as much unreacted acid as possible.
Second, saturated salt (sodium hydrogencarbonate & chloride) solution is more polar than solely water. Think of it: what would happen in solvent extraction if the aqueous layer is more polar in nature? What're the solubilities of the reactant and product in two phases?
2012-05-02 03:57:59 補充:
Remember the tert-butyl chloride is the desired product. It's sparingly soluble in water, and should be even less soluble in salt sol.
At the meanwhile, tert-butanol is already very soluble in water; increase in polarity of (extracting) solvent probably doesn't help much.