Acids and Bases(MC)

2012-03-18 6:35 am
請詳細解釋,其實我知ans ,但不知怎解,所以懇請各位詳細解釋,, 感激!!

1.When hydrogen chloride gas is dissolved in water,which of the following
species can be found in the resulting solution??
(1)H+
(2)Cl-
(3)OH-
A.(1) and(2)
B.(1) and(3)
C.(2) and(3)
D.(1),(2),(3) (ans) 那為何3種都有??

2.Which of the following hydroxides would react with both hydrochloric acid
and solium hydroxide??
A.Zinc hydroxide
B.Copper(II)hydroxide
C.Iron(II)hydroxide
D.Calcium hydroxide
問題:為何是那種hydroxides??

3.When sodium hydroxide solution is added into a solution of compound X,
a white ppt from.The ppt does not dissolve on the addition of excess alkali.
X may be
A.Calcium chloride
B.zinc nitrate
C.copper(II)sulphate
D.ammonium chloride
問題:為何是這答案??

4.Phosphoric acid is a tribasic acid with formula H3PO4.Which of the
following formulae represent the acid salts of Phosphoric acid ?
(1)Na3PO4
(2)KH2PO4
(3)(NH4)2HPO4
A.(1) and(2)
B.(1) and(3)
C.(2) and(3)
D. All of above
問題:為何是這答案??問題問咩??

5.Which of the following solutions when diluted will result in decreasing
conductivity but its pH value remains constant?
A.Sodium chloride solution
B.Ethanoic acid
C.Sodium hydroxide solution
D.Aqueous ammonia solution
問題:為何是這答案??問題問咩??

6.A sample of 0.09125g of hydrogen chloride is dissolved in distilled water and
made up to 250.0cm3.What is the pH value of the solution??
A.1
B.2
C.3
D.4

7.A solution has a pHvalue of 3.Which of the following conclusions can not
be deawn??
A.It liberates cabon dioxide when added to sodium carbonate solution
B.It tastes sour
C.It is a weak acid
D.It can conduct electricity

Thank a lot!!請各位詳細解釋,重點並不在ans!!!!

回答 (1)

2012-03-18 8:29 pm
✔ 最佳答案
1.D
3種ion都有係因為water自已會有self-ionization
H2O->H+ +OH- Kw=1*10^-14
姐係10^7粒水分子入面會有1粒轉做H+ ion同OH- ion
雖然好少,但係都係有
H+ ion同Cl- ions就唔洗解釋啦
2.A
4種hydroxide都會同acid react
但係得zinc hydroxide會溶係excess NaOH 去form一個complex ion
Zn(OH)2+2OH- ->[Zn(OH)4]2-

背後既原理好煩,F.4既話唯有死記果個表啦
3.A
calcium chloride會溶係水
CaCl2(aq)->Ca2+(aq)+2Cl-(aq)
之後當Ca2+遇上NaOH既OH-就會
Ca2+(aq) +2OH-(aq) -> Ca(OH)2(s)
生成slightly soluble既calcium hydroxide
溶唔晒係水既calcium hydroxide就係white precipitate喇
根據果個表,calcium hydroxide不溶於excess alkali,所以佢就係答案
4.D
其實acid溶係水並唔係一步登天爆晒d hydrogen ion出黎既
用H3PO4做例子
第一步:H3PO4->H2PO4- +H+
第二步:H2PO4- ->HPO4 2- +H+
第三步:HPO4 2- ->PO4 3-+ H+

當alkali唔夠,acid excess果陣就會form H2PO4-/HPO4 2- 既salt
當alkali excess果陣就會form PO4 3-既salt
但無論邊種salt係算係H3PO4既salt
5.A
conductivity係睇ion既concentration
1M既NaCl ion既concentration有2M
但dilute左e.g.10倍後就會變0.1M NaCl,ion concentration=0.2M
所以conductivity低左
但由於水同NaCl既pH都係7
你加幾多水都係7
所以加水pH不變但conductivity降低!
6.B
呢題應該assume HCl completely ionize in water
250cm^3 solution HCl既molarity
=[0.09125/(1+35.5)]/(250/1000)
=0.01M
由於1mole既HCl有1mole既H+,所以
H+既molarity=0.01M
pH=-log[H+]
pH=-log(0.01)
pH=2
7.C
deawn???you mean drawn?
睇pH係睇唔出strength of an acid
0.0000001M既HCl pH=6,但佢都係strong acid

希望幫到你,唔明歡迎再問!
參考: billyionaire


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