rate of the reaction mc

2012-03-06 10:09 pm
Which of the following changes will NOT increase the initial rate of the reaction between 50 cm3 of 1 M HCl(aq) and excess calcium carbonate granules ?

A. using 100 cm3 of HCl(aq) instead of 50 cm3 of HCl(aq)
B. using 2 M HCl(aq) instead of 1 M HCl(aq)
C. using 25 cm3 of 2 M HCl(aq) instead of 50 cm3 of 1 M HCl(aq)
D. using calcium carbonate powder instead of calcium carbonate granules

回答 (1)

2012-03-07 1:43 am
✔ 最佳答案
The answer is : A.using 100 cm³ of HCl(aq) instead of 50 cm³ of HCl(aq)

The main concept in options A, B and C is that concentration is a factoraffecting the initial rate, but not the volume of the solution (providing allsolid reactant(s) is/are immersed in the solution). A higher concentration means that there is agreater number of reactant particles in each unit volume of the solution, andthis will cause more frequent collisions between the reactant particles leadingto a faster rate. However, in case of differentvolumes of solution of the same concentration, there are equal numbers ofreactant particles in each unit volume of the two solutions.

A. The initial rate is the same as the solutions used are of the sameconcentration, although their volumes are different.

B. The initial rate is increased as HCl used is in higher concentration.

C. The initial rate is increased as HCl used is in higher concentration, despitesmaller volume.

D. The initial rate is increased as the surface area of the solid reactant isincreased.
參考: 土扁


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