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There is/are ...
"there" (or "here") in this kind of sentence is actually not the real subject of the sentence. It is called expletive constructions (填補). The real subject is after the verb (to be).
The rule of subject-verb agreement is:
With these constructions, the subject follows the verb but still determines the number of the verb.
That is to say, if the subject is plural, we use a plural verb (are, were).
Both of your sentences have plural subjects, so we use plural verbs.
(1) There are a bottle and a book on the desk.
==> A bottle and a book are on the desk.
(2) There are an orange and two apples in the basket.
==> An orange and two apples are in the basket.