✔ 最佳答案
You are right to state that electronegative difference between P and H is nearly zero. However, we notice that the dipole moment still cannot be cancelled out each other because of it's trigonal pyramidal shape. So it is slightly polar or nearly non-polar in nature. I guess you are mislead by the bond angle of NH3, which is also 107.
Since N is more electronegative than P, the N-H bonds is more polar than P-H bonds in their molecule. So the bond pair - bond pair repulsions between N-H bonds are much stronger than those in P-H bonds. So N-H bonds repel stronger with each other than P-H bonds. Thus NH3 should have a higher bond angle than PH3.
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