✔ 最佳答案
In [AlH4]^-, Al is covalently bonded with 4 H atoms, which requires 4 outmost shells electrons in Al to take place, however, we notice that there are only 3 outmost electrons in Al, thus 1 electron from others is received. (So you can notice there is 1- on the upper right-hand corner of [AlH4]^-)
In [NH4]^+, similarly, N is covalently bonded with 4 H atoms, which requires 4 outermost shells electrons in N to take place, however, we notice that there are 5 outmost electrons in N, thus 1 electron is lost to others. (So you can notice there is 1+ on the upper right-hand corner of [NH4]^+)
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