✔ 最佳答案
remember the alkylation of amines:
>NH + RI ------> >NR + HI
NR3 + RI ------> NR4(+) I(-)
when the amine has hydrogen, the alkyl group replaces the hydrogen, giving the alkyl on amine; hydrogen iodide is also produced.
also notice that the product is a base while HI is acidic. unless there's other reagents to neutralize the acid OR carry out treatment after synthesis, a salt would be produced.
when the amine has NO hydrogen, alkyl group still attaches to nitrogen. however, no HI can be eliminated, thus a quaternary ammonium ion is produced, with iodide as counter-anion.
this reaction involves nucleophilic substitution reaction, requiring lone-pair on nitrogen.
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