oxidation states of halogens

2010-10-02 6:28 am
about variable oxidation states of halogens...


* - F cannot exhibit variable oxidation states because::
(a)it is the most electronegativity atom.
(b)it has no low lying vacant d-orbitals to expand octet.

- the other halogens exhibit a positive oxidation states.these are due to promotion of electrons from p-orbitals into lying vacant d-orbitals*

i dont get the meaning of..
" low lying vacant d-orbitals to expand octet"
&"promotion of electrons from p-orbitals into lying vacant d-orbitals"=.=

help me ,please!!@@

回答 (1)

2010-10-02 7:12 am
✔ 最佳答案
that's easy. think about the structures of oxyanions of the halogens, like chlorine(V) fluoride (chlorine pentafluoride, ClF5), a square pyrimidal molecule.

clearly, with only one singly-occupied 3d orbital, chlorine is unable to form 5 bonds as well as accomodate a lone pair. thus, it undergoes sp3d2 hybridization and yields six new orbitals -- 5 singly-occupied, 1 fully-occupied. the five orbitals enables chlorine to form 5 bonds wit 5 fluorine atoms.

similar for other (non-diatomic) interhalogens.

that's the trick. you need vacant low-lying orbitals for hybridization for more vacancies. chlorine, bromine and iodine can do this, but fluorine can't. low-lying favors promotion of electrons to those orbitals, followed by hybridization.



收錄日期: 2021-04-19 23:18:55
原文連結 [永久失效]:
https://hk.answers.yahoo.com/question/index?qid=20101001000051KK01699

檢視 Wayback Machine 備份