Basicity of an acid

2010-09-19 10:45 pm
There is a very old question on the calculation of the basicity of an acid but I think it is worthwhile asking it.

0.75 gram of an acid of molecular weight (i.e. molecular mass) 90 is required for
neutralisation of 16.67 c.c. of a normal sodium hydroxide solution. Calculate the
basicity of the acid.

Please show the workings clearly and explain the principles behind. Thank you.

回答 (1)

2010-09-20 2:09 am
✔ 最佳答案
this question is not old; i think it'll be ask in the future.

no. of mole of acid = mass / molar mass = 0.75g / 90g.mol^-1 = 0.008333mole
let molecular formula of the acid be HyA, where y is the basicity (i.e. max. no. of ionizable hydrogen per molecule of acid), A(y-) is the anion of the acid after complete neutralization (with negative charge of y).

but wait! you haven't supply the concentration of sodium hydroxide solution.
let C (mol.dm^-3) be the conc. of NaOH sol.
equation of reaction:
HyA + yNaOH ------------> NayA + yH2O

no. of mole of NaOH consumed = volume x molar concentration (mind the unit conversion!)
= (16.67/1000) x C = 0.01667Z mole
mole ratio of HyA:NaOH = 0.008333:0.01667C

however, according to equation, mole ratio of HyA:NaOH = 1:y

then you can figure out what y is, given that you get the value of Z:
0.00833/0.01667C = 1/y



2010-09-20 22:06:01 補充:
"normal" solution probably means 1 M solution. i've checked the wikipedia, but you should check this with your teacher.
C=1, then y=2, ie basicity of acid is 2.


收錄日期: 2021-04-13 17:31:24
原文連結 [永久失效]:
https://hk.answers.yahoo.com/question/index?qid=20100919000051KK01007

檢視 Wayback Machine 備份