SS1 Chem ~~~~~~~~~~~~~~~~~~~~~

2010-05-09 9:18 pm
For the formation of Zinc hydroxide, why do some precipitates formed
re-dissolve in excess NaOH (aq) or in excess NH_3 (aq)?

回答 (1)

2010-05-09 9:32 pm
✔ 最佳答案
Solid Zn(OH)2 can dissolve in excess strong alkali, because Zn(OH)2 is amphoteric which can neutralize both strong acids and both strong alkalis to form soluble salt.
Zn(OH)2(s) + 2NaOH(aq) → Na2[Zn(OH)4](aq)
or: Zn(OH)2(s) + 2OH^-(aq) → [Zn(OH)4]^2-(aq)

Solid Zn(OH)2 can dissolve in excess NH3 solution, because they react to form a soluble complex.
Zn(OH)2(s) + 4NH3(aq) → [Zn(NH3)4](OH)2(aq)
or: Zn(OH)2(s) + 4NH3(aq) → [Zn(NH3)4]^2+(aq) + 2OH^-(aq)
參考: wanszeto


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