Combined Science Chem

2010-05-08 4:04 am
1.Titanium can be extracted from titanium(IV) oxide (TiO2). The extraction consists of two step:
1.TiO2(S) --C(s), Cl(g) --> TiCl4(g)
2.TiCl4(g) -- Mg (L) -->Ti(s)
a) Decide whether titanium or magnesium is more reactive. Explain your answer.
b) In a certain experiment, 11.4 g of TiCl4 were allowed to react with excess Mg 2.54 g of Ti were obatined. What was the percentage yield of Ti? (Relative atomic masses: Mg = 24.3, Cl = 35.5, Ti = 47.9)

2.The following set-up was used to determine the empirical formula of an oxide of Cobalt.
http://farm5.static.flickr.com/4021/4586543476_415055c3d2_b.jpg
The experimental results were as follows:
(1)Mass of crucible + lid = 20.49 g
(2)Mass of crucible + lid + cobalt = 23.13 g
(3)Mass of crucible + lid + oxide of cobalt = 24.09 g
a) give a reason why the crucible should be covered with the lid during heating, as shown in the diagram.
b) Coblat-60 is widely used as a medical source. Find the number of protons and number of neutrons of a 60Co atom.
c) Coblat has a hydrated chloride with the chemical formula CoCl2.nH2O. On strong heating, 22.0 g of the chloride produced 9.99 g of water. What is the value of n? (Relative atomic masses: H = 1.0, O = 16.0, Cl = 35.5, Co = 58.9)

回答 (1)

2010-05-09 6:40 am
✔ 最佳答案
1.
a)
Magnesium is more reactive than titanium.
This is because magnesium displaces titanium from TiCl4 in step 2.

b)
Mole ratio TiCl4 : Ti = 1 : 1

Molar mass of TiCl4 = 47.9 + 35.5x4 = 189.9 g/mol
No. of moles of TiCl4 used = 11.4/189.9 = 0.06003 mol
No. of moles of Ti = 2.54/47.9 = 0.05303
% yield of Ti = (0.05303/0.06003) x 100% = 88.3%


2.
a)
This is to prevent the solid (the oxide of cobalt and the cobalt formed) inside the crucible from spilling out during heating.

b)
From the Periodic Table, atomic number of cobalt = 27
No. of protons in a 60Co atom = 27
No. of neutrons in a 60Co atom = 60 - 27 = 33

c)
Molar mass of CoCl2 = 58.9 + 35.5x2 = 129.9 g/mol
Molar mass of H­2O = 1x2 + 16 = 18 g/mol

Mole ratio CoCl2­ : H2O
= (22 - 9.99)/129.9 : 9.99/18
= 0.0925 : 0.555
= 1 : 6

Hence, n = 6
參考: wanszeto


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