✔ 最佳答案
It's in Ice Path. When you enter Ice Path going to Blackthorn City, there is a small patch of ice, then a large one. Get across the large one and there will be a choice to go up or down. Go down and there will be another patch of ice with a poke ball at the right end. This poke ball contains Waterfall.
Of course, I'm doing this from memory. I haven't played Gold in 5 years or more. The location is correct, but the placement may be a little off.