in case you improve the wavelength of incident radiation , the form of photoelectrons does no longer exchange because of fact the form of photoelectrons matter in basic terms on the intensity of sunshine,no longer its frequency.
Electrons are negative, protons are positive and neutrons are neutral. If you take an atom of a metal e.g. Na, and knock off an electron, the charge will be imbalanced. As the number of protons and electrons in a neutral atom are equal, losing an electron, (or negative charge), will cause the atom to become positive
e.g. Na loses e- = Na+
Na+ loses e- = Na2+
etc........