F.4 Chemistry(Moles)

2009-11-30 2:34 am
About percentage Yield=actual yield / theoretical yield x 100%

Question:
100cm^3 of barium chloride solution of concentration 0.0500 mol dm^-3 were treated with an excess of sulphate ions in solution. The precipitate of barium sulphate formed was dried and weighed. A mass of 1.1558g was recorded. What percentage yield does this represent?

Ans:99.2%
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回答 (1)

2009-11-30 9:45 am
✔ 最佳答案
Ba^2+(aq) + SO4^2-(aq) → BaSO4(s)
Mole ratio Ba^2+ : BaSO4 = 1 : 1

No. of moles of BaCl2 used = 0.0500 x (100/1000) = 0.005 mol
No. of moles of Ba^2+ used = 0.005 mol
Maximum no. of moles of BaSO4 formed = 0.005 mol
Molar mass of BaSO4 = 137.3 + 32.1 + 16x4 = 233.4 g/mol
Maximum mass of BaSO4 formed = 0.005 x 233.4 = 1.167 g
Percentage yield = (1.1558/1.167) x 100% = 99.0%

(The answer is not 99.2%)
(If 1.1558 g is replaced by 1.159 g, the answer will be 99.2%)


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