普通化學 有關熱力學

2009-07-12 7:42 pm
題目
For a certain process, at 300k, ΔG=-10KJ and ΔH=-7KJ. If
the process is carried out so that no useful work is performed
,ΔG is
1.+10 kJ
2.+7 KJ
3.0 KJ
4.-7KJ
5.-10KJ

希望為的人解一下,謝謝

回答 (2)

2009-07-14 1:02 am
✔ 最佳答案
安安 你參考一下
當定溫下(constant temperature)
△G=△H-T△S 如題反應過程已完成(the process is carried out)
表示已達到平衡則△G=0 kJ(Neither the forward nor the reverse reaction prevails (Equilibrium))
此時δW=pdV=0(the work done by the system in a reversible process)
△H=T△S=-7kJ
因此 答案應為 3. △G=0 kJ
2009-07-13 1:20 am
In the question, ΔG of the process -10 kJ.

Therefore, the answer is ΔG = -10 kJ


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