Bad debts means the amount already irrecoverable from the debtors. The amount is immediately written off from the debtors' balance and recognized as an actual expense in Profit and Loss Account.
Doubtful debts means the amount are not certain and just an estimate from the past experience that a certain percentage of debts may be bad at the end. In accounting, as a principle of prudence, we usually provide a certain percentage on the total amount of the debtors as bad and / or doubtful. In balance sheet, we usually present it as Debtors less Provision for Bad and Doubtful Debts.