I think the relation of pi with circles in two aspects as following:
Firstly, the perimeter of a circle is equal to two times pi and radius,
i.e. perimeter=2πr where r is the radius of a circle.
Secondly, the area of a circle is equal to pi times the square of radius,
i.e. area=πr^2 where r is the radius of a circle.
Blessings,
Samuel Lai Tze Cheong.