✔ 最佳答案
Consider the electromagnetic spectrum, the energy is higher on the blue end and lower on the red end. For monochromatic light, blue flame is releasing more energy than the red flame.
For "white" light, it is composed of light across the whole spectrum. It is a mixture of different light. So white hot flame is only achievable when the flame release energy at different energy level, generating light in different colour at the same time.
In most situation, this does not happen. If you burn a fuel / material, the energy release is governed by the atomic / electronic configuration of the fuel / material, and only light of one or a few energy level is released. As a result, you can only have flame in a monochromatic colour. As said before, blue end has higher energy and thus blue frame is hottest. White hot is still the hottest (the reaction happens at the SUN), but it is unlikely to have white hot flame in laboratory environment.