Titration Question help!

2009-02-22 8:22 pm
1.620g of solid oxalic acid dihydrate (H2C2O4-H2O) is used to make a primary standard acid by dissolving in water to a volume of 250.0ml.
22.73ml of NaOH is required to neutralize 25.00ml of the primary standard acid.
12.65ml of this now standardized NaOH is required to neutralize 10.00ml of unknown HCl
What is the concentration of the HCl?

Show all work please! Thank you!
更新1:

Oh sorry, thanks for the corrections. it's H2C204-2H2O

回答 (2)

2009-02-22 8:45 pm
✔ 最佳答案
H2C2O4‧H2O + 2NaOH ---> Na2C2O4 + 3H2O --- ( 1 )
NaOH + HCl ---> NaCl + H2O --- ( 2 )
No. of moles of oxalic acid in 250ml solution:
1.620 / ( 1.0 x 2 + 12.0 x 2 + 16.0 x 4 + 1.0 x 2 + 16.0 )
= 0.015mol
No. of moles of oxalic acid in ( 1 ): 0.015 x 25 / 250 = 1.5 x 10-3 mol
No. of moles of NaOH in ( 1 ): 1.5 x 10-3 x 2 = 3 x 10-3 mol
Molarity of NaOH: 3 x 10-3 / ( 22.73 / 1000 ) = 0.132M
No. of moles of NaOH in ( 2 ): 0.132 x 12.65 / 1000 = 1.67 x 10-3 mol
Molarity of HCl in ( 2 ): 1.67 x 10-3 / ( 10.00 / 1000 ) = 0.167M

2009-02-22 19:19:15 補充:
Correction: No. of moles of oxalic acid:
1.62 / ( 2 + 12 x 2 + 16 x 4 + 2 x 18 ) = 0.0129
No. of moles of oxalic acid in 25ml: 0.0129 x 25 / 250 = 1.29 x 10^-3
No. of moles of NaOH: 1.29 x 10^-3 x 2 = 2.57 x 10^-3

2009-02-22 19:19:27 補充:
Molarity of NaOH: 2.57 x 10^-3 / ( 22.73 / 1000 ) = 0.113M
No. of moles NaOH in 2: 0.113 x 12.65 / 1000 = 1.43 x 10^-3
Molarity of HCl: 1.43 x 10^-3 / ( 10 / 1000 ) = 0.143M

2009-02-22 19:21:25 補充:
Thx for reminding. I didn't realize it while I was doing the calculation.
But jackiii_iii please kindly check your Q before you post it=]
參考: My Chem Knowledge
2009-02-22 10:04 pm
The formula of oxalic acid dihydrate should be H2C2O4•2H2O instead of H2C2O4•H2O. Due to this mistake in the question, Gabriella Montez got a small mistake in calculating the molar mass of the acid.


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