Diamond Vs Graphite

2009-02-22 10:51 am
The enthalpy change of combustion of diamond at 298K is
- 395.4 kJ mol^-1 .
The enthalpy change of combustion of graphite at 298K is
- 393.5 kJ mol^-1 .

Which allotrope of carbon, diamond or graphite is energetically more
stable ? Explain why carbon does not convert from the less stable
allotrope to the more stable one at room temperature.

回答 (1)

2009-02-22 11:18 am
✔ 最佳答案

C(diamond) + O2(g) → CO2(g) --DH = -395.4 kJ mol-1
CO2(g) → C(graphite) + O2(g) --DH = +393.5 kJ mol-1

Add the two equations together:
C(diamond) → C(graphite) --DH = -1.9 kJ mol-1
It is exothermic. Therefore, graphite is energetically more stable.

Carbon does not convert from diamond to graphite at room temperature. This is because the activation energy is very high, as the C-C bonds are very strong and a lot of energy is needed to break them.
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