You first need to identify a few things:
1. What is the daily caloric need for those children. And do you use the minimum number to sustain life or a larger number of calories that would help them thrive. Rice provides carbohydrates, but very little protein and fats - and hardly any vitamins or minerals. It may keep death away for a while - but if the person only ate rice it would result in malnutrition pretty quickly. So you may have to ignore some facts in your statement about how rice alone would help world hunger.
2. Establish if your jar is going to contain cooked or raw rice - and how many calories of rice that jar contains.
3. Find out how much rice your jar contains, to figure out how many calories are in that jar.
With those data points, you can figure out the rest. You might want to start your research at:
http://www.freerice.com/ which allows you to play a fun vocabulary game and donate rice at the same time.
Good luck!