chemical displacement

2008-12-31 8:00 pm
definition of displaement from my book.

1. If a more reactive metal is put into a salt solution of a less reactive metal, then the more ractive metal will take the place of the less reactive metal.
2.The displaced metal (i.e. less reactive metal) then coats itself onto the more reactive metal.
3. Once the more reactive metal has been completely coasted with the less reactive metal, the reaction stops.

I dont understand what it meams by 'coat'. i know the word but i dont understand how can the less reactive metal coat itself onto the more reactive metal, which has already reacted with the solution and become a salt.

or you can just give me another definition of the term, with EXPLANATION.

Pls, dont copy from wiki.

回答 (1)

2008-12-31 10:06 pm
✔ 最佳答案

Definition of displacement in aqueous solution:
"Displacement is a reaction at which a more reactive metal displaces a less reactive metal from the solution of its salt."
For example, When a piece of copper (a more reactive metal) is put into silver nitrate solution (the solution of a salt of a less reactive metal), displace reaction occurs. In the displacement reaction, copper is changed (oxidized) to copper(II) nitrate solution and silver nitrate solution is changed (reduced) to silver metal, i.e.
Cu(s) + 2AgNO3 → Cu(NO3)2(aq) + 2Ag(s)
or: Cu(s) + 2Ag+(aq) → Cu2+(aq) + 2Ag(s)

In the passage, "coat" means "form a layer on the surface of". For example, "silver coats on copper" means "a layer of silver is formed on the surface of copper which has not yet been reacted". Note that before the end of the reaction, part of the more reactive metal is unreacted.

You have given 3 points of definition of displacement. The first point is part of the definition. The second and the third points are the description of the experiment. Actually, the second and the third points are incorrect. In the experiment, the less reactive metal formed is not a layer, but just some solid stuck on the surface of the more reactive metal. The solid is easily detached from the more reactive metal when the test tube is shaken. Therefore, if the more reactive metal is the limiting reactant, the reactive metal would be completely reacted (dissolved) at the end of the reaction.
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參考: My chemistry knowledge - U level


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