(CH3)3CCH2Cl , 1'RCL , doesn't participate in typical SN

2008-11-10 12:23 am
F.7___(CH3)3CCH2Cl , 1'RCL , doesn't participate in typical SN2 reactions

I know the reason is that there is steric effect
I don't understand why it doesn't participate in elimination but SN1

THX!!!1
更新1:

why does CH3CH=CHCl react with AgNO3 more strongly than CH2=CHCH2Cl ????

回答 (2)

2008-11-10 6:23 pm
✔ 最佳答案
(CH3)3CCH2Cl , steric effect is a factor, another reason is that the CH3 group is a electron donating group, 3 CH3 groups will push the electron of C-CH2Cl bond closer to the C of CH2Cl, then Cl is easily form Cl- since the electronegativity of Cl is higher than C. Then a Carbonium ion (CH3)3CCH2 is form.


why does CH3CH=CHCl react with AgNO3 more strongly than CH2=CHCH2Cl ????

Ans: Similary , you try to solve it.
參考: me
2008-11-13 6:53 am
Are you sure CH3CH=CHCl reacts with AgNO3 stronger than CH2=CHCH2Cl ?

The fact should be that CH2=CHCH2Cl reacts with AgNO3 stronger than CH3CH=CHCl,
so I propose you should check your book.


收錄日期: 2021-04-21 17:47:43
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