旋光計(polarimeter)係咪癈?

2008-10-17 11:26 pm
旋光性物質是屬於對映異構
而對映異構物質中物理性質是相等的
即我無法將其分開左旋及右旋物

假如我將某物質反應進行旋光測試
如果生成物是有旋光性,那便會有2種-左及右旋物
那旋光計變不會轉動,
更什者,我怎可以用旋光計來追蹤反應進行?
因奕光計只時不停左右搖動,
理想下,最終沒有偏轉

即係旋光計係癈....?
更新1:

我好像問得不太好... 我想問的是就Optically active samples黎講... polarimeter 係咪癈.. 重點係:係反應入中有機會同時生成左及右旋 咁旋光計便好似無咩用...

回答 (3)

2008-10-17 11:58 pm
✔ 最佳答案
in fact,it's not a 癈's stuff,it'sthe measurement and interpretation of the polarization of transverse waves, most notably electromagnetic waves, such as radio waves and light. Typically polarimetry is done on electromagnetic waves that have traveled through or reflected, refracted, or diffracted from some material or object in order to characterize that object.

A polarimeter is the basic scientific instrument used to make these measurements, although this term is rarely used to describe a polarimetry process performed by a computer, such as is done in polarimetric synthetic aperture radar.

Polarimetry of thin films and surfaces is commonly known as ellipsometry.

Polarimetry can be used to measure various optical properties of a material, including linear birefringence, circular birefringence (also known as optical rotation or optical rotary dispersion), linear dichroism, circular dichroism and scattering.


Polarimetry can also be included in computational analysis of waves. For example, radars often consider wave polarization in post-processing to improve the characterization of the targets. In this case, polarimetry can be used to estimate the fine texture of a material, help resolve the orientation of small structures in the target, and, when circularly-polarized antennas are used, resolve the number of bounces of the received signal (the chirality of circularly polarized waves alternates with each reflection).

by the way,Optically active samples, such as solutions of chiral molecules, often exhibit circular birefringence. Circular birefringence causes rotation of the polarisation of plane polarised light as it passes through the sample.


hope this can help you!

2008-10-17 15:58:29 補充:
A simple polarimeter to measure this rotation consists of a long tube with flat glass ends, into which the sample is placed. At each end of the tube is a Nicol prism or other polarizer.

2008-10-17 15:59:07 補充:
The specific rotation of the sample may then be calculated. Temperature can affect the rotation of light which should be accounted for in the calculations

2008-10-17 15:59:30 補充:
hope this can help you

2008-10-17 16:01:55 補充:
嗯,可能你需要一個中文的吧,ok,就這樣:
性质:又称偏振计。测量偏振光通过旋光性物质后的旋转角度的仪器。主要构成部分是起偏振器(如尼科尔棱镜)和检偏振器(如尼科尔棱镜)。当它们处于一定的位置时,视场的两半照度相等。如果在它们中间放置旋光性物质,则视场的两半照度发生变化,旋转检偏振器使两半照度重新相等,读出旋转角度的大小并算出被测物质的比旋度。旋光度与旋光性物质的分子结构、溶液的浓度和温度、溶剂的性质、光的波长等有关。旋光计常用于检定物质的纯度、测定溶液的浓度以及鉴别光学异构体等。旋光测糖计或糖量计是专门用于测定糖溶液浓度的一种旋光计。
參考: me and some wiki
2008-10-19 1:14 am
分離方法係...?
仲有隻純左/右旋物是怎那出來的....?
2008-10-18 8:48 am
其實係有辦法把左旋和右旋分離的
如果加進一隻純左旋或純右旋的溶劑(e.g.丁-2-醇)
當然兩隻都會溶,但其中一隻由於是結構排列不整齊的關係~其飽和度略低
因此透過溶解度可以把左旋和右旋分離出來


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