✔ 最佳答案
You have to find out his exact title and use it in your letter.
It is not appropriate to call him sir or Mr. xxx, etc.
Your must call him in his title because this letter is a formal letter, especially true in the political and academic fields.
If his is a 院長, you should say :
Dear Mr. Dean of ??? Faculty,
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I am sorry to be that serious but you cannot make such mistake in this kind of letter. We always address people with his title like below :
Dear Mr. President
Dear Mr. Principal
Dear Master of College