✔ 最佳答案
1)
+) MnO4- + e- → MnO42- 2- + 2H2O + 2e- (x2
+) MnO2 + 2H2O → MnO42- + 4H+ + 2e- (x1
2MnO4- + MnO2 + 2H2O → 3MnO42- + 4H+
Actually, the reaction must be done in a strong alkaline medium.
The equations should be:
+) MnO4- + e- → MnO42- 2- + 2H2O + 2e- (x2
+) MnO2 + 4OH- → MnO42- + 2H2O + 2e- (x1
2MnO4- + MnO2 + 4OH- → 3MnO42- + 2H2O
=====
2)
+) Mn3+ + 2H2O → MnO2 + 4H+ + e- (x1
+) Mn3+ + e- → Mn2+ O2 + 4H+ + e- (x1
2Mn3+ → MnO2 + Mn2+ + 4H+
=====
3)
+) Cl2 + 2e- → 2Cl- ClO3- + 6H2O + 10e- (x5
+) Cl2 + 12OH- → 2ClO3- + 6H2O + 10e- (x1
6Cl2 + 12OH- → 10Cl- + 2ClO3- + 6H2O
Divide both sides by 2:
3Cl2 + 6OH- → 5Cl- + ClO3- + 3H2O
=====
4)
+) Br2 + 2e- → 2Br- ClO3- + 6H2O + 10e- (x5
+) Br2 + 12OH- → 2BrO3- + 6H2O + 10e- (x1
6Br2 + 12OH- → 10Br- + 2BrO3- + 6H2O
Divide both sides by 2:
3Br2 + 6OH- → 5Br- + BrO3- + 3H2O
=