about electrical conductivity !!!

2008-10-02 12:45 am
in the experiment of titration between H2SO4 and Ba(OH)2 by using electrical conductivity to determine its end point ,why an alternating current but not a direct current is used ?

回答 (1)

2008-10-02 1:59 am
✔ 最佳答案
Ba^2+(aq) + SO4^2-(aq) --> BaSO4(s)

The reaction decrease mobile ions, and conductivity of the solution decrease.

No matter DC or AC would get this result. ( decrease of conductivity )

But if DC is used. It would have a polarization effect. +ve ion migrate to one side and -ve ion migrate to another side. This is no good and affect the accuracy of the test. AC is better here.


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