Deoxygenation is a chemical reaction involving the removal of molecular oxygen (O2) from a reaction mixture or solvent, or the removal of oxygen atoms from a molecule.
Classic representatives of deoxygenation are:
the replacement of a hydroxyl group by hydrogen (A-OH → A-H) in the Barton-McCombie deoxygenation
the replacement of an oxo group by two hydrogen atoms (A=O → A) in the Wolff-Kishner reduction
A chemical reagent for the deoxygenation of many sulfur and nitrogen oxo compounds is the trifluoroacetic anhydride / sodium iodide combination [1] for example in the deoxygenation of the sulfoxide diphenylsulfoxide to the sulfide diphenylsulfide:
圖片參考:
http://upload.wikimedia.org/wikipedia/en/thumb/f/f5/SulfoxideDeoxigenation.png/400px-SulfoxideDeoxigenation.png
The reaction mechanism is based on activation of the sulfoxide by a trifluoroacetyl group and oxidation of iodine. Iodine is formed quantitatively in this reaction and therefore the reagent is used for the analytical detection of many oxo compounds.
圖片參考:
http://upload.wikimedia.org/wikipedia/en/thumb/e/e6/TFAA_deoxigenationMechanism.png/400px-TFAA_deoxigenationMechanism.png
2008-05-15 22:12:58 補充:
No oxygen is inside the blood.