F.5 Chem

2008-04-28 9:14 am
One mole of each of the following compounds is burnt completely in oxygen. Which compound requires the greatest volume of oxygen , measured at the same temperature and pressure , for complete combustion?
A. Carbon monoxide
B. ethane
C. ethene
D. ethanol

回答 (2)

2008-04-28 9:30 am
✔ 最佳答案
The answer is B.

Under constant temperature and pressure, the greater the number of moles of a gas, the greater is its volume. (Avogadro’s law)

A. 2CO + O2 → 2CO2
Mole ratio CO : O2 = 2 : 1
No. of moles of O2 required = 1 x (1/2) = 0.5 mol

B. 2C2H6 + 7O2 → 4CO2 + 6H2O
Mole ratio C2H6 : O2 = 2 : 7
No. of moles of O2 required = 1 x (7/2) = 3.5 mol

C. C2H4 + 3O2 → 2CO2 + 2H2O
Mole ratio C2H4 : O2 = 1 : 3
No. of moles of O2 required = 1 x 3 = 3 mol

D. CH3CH2OH + 3O2 → 2CO2 + 3H2O
Mole ratio CH3CH2OH : O2 = 1 : 3
No. of moles of O2 required = 1 x 3 = 3 mol
2008-04-28 9:09 pm
Perhaps It maybe C
The percentage by mass of Carbon in the molecules becomes larger, it will be more difficult to completely combust, the more oxygen is need to combust it completely.

A: 12/(12+16)x100% = 42.9%
B: 24/(24+6) x100% = 80%
C: 24/(24+4) x 100% = 85.7%
D: 24/(24+16+5+1) x 100% = 52.2%

Therefore, C is the answer.

有錯請指教


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