✔ 最佳答案
It is mainly depends on Ligand stregth of the ligand
Ligand strenght depends on (a)basic strength and (b) no of atoms which have lone pair that can donate
Usually basic strenght increase imply Ligand strenght increase
Usually no of atoms which have lone pair that can donate increase imply Ligand strenght increase
because of the change in entropy
eg ECTA>>N2O, (C2O4)^2-
Minor factor such as pH (low pH may lead the protonation of the Donor atoms)
2008-04-26 16:58:57 補充:
series : CO> CN->NO2>EDTA4->HN2-CH2-CH2-NH2>NH3> NCS-> H2O>(C2O4)2->F->OH->Cl->br->I-