✔ 最佳答案
In aqueous KOH state, there are plenty of hydroxide ions formed. The OH- favors the nucleophilic substitution of the halide to form the ROH.
In ethanolic KOH state, instead of forming hydroxide ions, the hydroxide ions will react with the ethanol to form ethanoxide ion: HO- + EtOH = H2O + EtO-. In fact, this ethanoxide is not a good substitute to replace the halide but it rather acts as a strong base to remove the proton from the alkyl group of the haloalkane. In such case, it favors the elimination reaction rather than the substitution reaction.
R-CH2-CH2-Cl = {R-CH-CH2Cl]- = R-CH=CH2 + Cl-
Howeever, it also depends on whether there is any acidic proton in the haloalkane.
I hope you understand what I mean.