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Bicarbonate
Bonding within the molecules: Covalent bond
Properties
A bicarbonate salt forms when a positively charged ion attaches to the negatively charged oxygen atoms of the ion, forming an ionic compound.
Many bicarbonates are soluble in water at standard temperature and pressure, particularly sodium bicarbonate and magnesium bicarbonate; both of these substances contribute to total dissolved solids, a common parameter for assessing water quality.
Silicic acid
Silicic acid is a general name for a family of chemical compounds of silicon, hydrogen, and oxygen, with the general formula [SiOx(OH)4-2x]n.
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Some simple silicic acids have been identified in very dilute aqueous solution, such as metasilicic acid (H2SiO3), orthosilicic acid (H4SiO4, pKa1=9.84, pKa2=13.2 at 25° C), disilicic acid (H2Si2O5), and pyrosilicic acid (H6Si2O7); however in the solid state these probably condense to form polymeric silicic acids of complex structure.
Silicic acids may be formed by acidification of silicate salts (such as sodium silicate) in aqueous solution. When heated they lose water to form silica gel, an active form of silicon dioxide.
Sulphate
Bonding within the ion: Covalent bond
Properties
Many examples of ionic sulfates are known, and many of these are highly soluble in water. Exceptions include calcium sulfate, strontium sulfate, and barium sulfate, which are poorly soluble. The barium derivative is useful in the gravimetric analysis of sulfate: one adds a solution of, perhaps, barium chloride to a solution containing sulfate ions. The appearance of a white precipitate, which is barium sulfate, indicates that sulfate anions are present.
The sulfate ion can act as a ligand attaching either by one oxygen (monodentate) or by two oxygens as either a chelate or a bridge.[1] An example is the neutral metal complex PtSO4P(C6H5)32 where the sulfate ion is acting as a bidentate ligand. The metal-oxygen bonds in sulfate complexes can have significant covalent character.