✔ 最佳答案
pH value 可以同溫度有關...
Please looking below acid equilibrium system:
HA (aq) + H2O (l) ↔ A─ + H3O+ △H is positive value
HA is a strong acid
A─ is anion
H3O+ is hydroxonium ions
△H is enthalpy change (energy change)
The forward reaction is enothermic(吸熱的) reaction,
When temperature increases, the equilibrium position will shifts to right to form more A─ and H3O+ ions. Because the forward reaction is energetically(能學) favourable at higher temperature.
So, the concentration of H3O+ will increases when the temperature increases.
Thus, the pH value will decreases when more H3O+ is formed
相反來說,
The temperature decreases, the forward reaction is not favourabe and the concentration of H3O+ will decreases.
Therefore, the pH value increases when less H3O+ is formed.
總括黎講...
只要一個酸鹼反應係涉及一個dynamic equilibrium, pH 值 就會同溫度掛拘.
I hope my answer can help you.
PS:本人英文唔好,所以會中英夾離,睇得辛苦就唔好意思^.^"