✔ 最佳答案
Yes, they have differences!!
For example:
A) City and citizens:
There are many citizens in this city.
City - the place in a country.
Citizens - the people live in the country.
B) Since and after
Examples:
1) Please do something for me SINCE you are free.
You cannot say "please do sth for me after u are free" (DOESN'T MAKE SENSE)
2) Please see me AFTER lunch.
cannot say "Please see me since lunch." (Also DOESNT MAKE SENSE)