為何在ecs找不到NO3-+2H++e- NO2+H2O

2007-12-14 6:36 am
為何在完整的 electrochemical series(http://www.digischool.nl/sk/Binas/elektrodepotentiaal.pdf)內卻找不到
NO 3-(aq) + 2H+(aq) + e- <--> NO2(g) + H2O(l)

回答 (1)

2007-12-15 8:07 pm
✔ 最佳答案
2NO3-(aq) + 4H+(aq) ---> N2O4(g) + 2 H2O(l)
     -   +
〔2NO  +4H 〕,〔N O +2H O〕 |Pt
    3         2 4   2
Standard electrode potential = 0.8 V
N2O4 <=> NO2
Higher temperatures push the equilibrium towards nitrogen dioxide.
I hope this can help with your understanding. =)
參考: My knowledge


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