methanol and propanol

2007-11-09 8:21 pm
why propanol can release more enthalpy during combustion than that of methanol?
and does it means that the more enthalpy can be released, the more efficient fuel it is?
thank you~

回答 (1)

2007-11-09 8:46 pm
✔ 最佳答案
Combustion of Methanol :

CH3-OH + 3/2 O2 => CO2 + 2 H2O

Combustion of Propanol :

C3H7-OH + 9/2 O2 => 3 CO2 + 4 H2O

Since 1 mole of propanol can systhesis 3 mole of carbon dioxide and 4 mole of water , in which the systhesis of CO2 and H2O is an exothermic reaction , combustion of propanol can release more energy than methanol per mole .
Ofcourse , you will need to calculate the " Born Harbor Cycle " in order to find out the acute enthalpy changed per mole during combustion of propanol and methanol .

Finally , it is not always true that more energy released = more efficient . It is , because of the "effcient" is based on at least two critiria :
I) Is it the fuel easy enough to be combusted ?
II) The enthalpy change per unit mass of fuel

In (I) , many long chain-organic compound can release even more energy during combustion than propanol , but they're not so easy to be burnt , so they're not effcient .
In (II) , you will need to calculate [energy released/mass] of the fuel , since every compound have different Molar mass , 1 mole of each compound has different mass than the others .


收錄日期: 2021-04-13 14:24:09
原文連結 [永久失效]:
https://hk.answers.yahoo.com/question/index?qid=20071109000051KK00980

檢視 Wayback Machine 備份