Nitric Acid 100%

2007-11-07 2:15 am
想問有關硝酸的問題﹐我實在搞不清楚硝酸的名稱與種類﹐因為好像百分比稍微有些不同﹐就有不同的名稱。

1) 大於等於98%的硝酸就是指發煙硝酸﹐那麼如果100%的硝酸的意思是否有兩種叫法? 一可以稱為發煙硝酸 (因為只要是大於等於98%)﹐二來也可稱為純硝酸 ??

2) 100%硝酸是否帶有nitrogen oxides ?

3) 那麼100%硝酸如帶有nitrogen oxides的話﹐在什麼情況下才能完全去掉nitrogen oxides?

感謝萬分。

回答 (1)

2007-11-17 1:33 am
✔ 最佳答案
1)都是發煙硝酸
The pure acid tends to give off white fumes when exposed to air, leading to the common name "fuming nitric acid
2)硝酸可以不帶有nitrogen oxides,是透明液體。當帶有nitrogen oxides,才變成黃色的。
Pure anhydrous nitric acid (100%) is a colorless liquid with a density of 1522 kg/m^3 which solidifies at -42 deg C to form white crystals and boils at 83 deg C. When boiling in light, even at room temperature, there is a partial decomposition with the formation of nitrogen dioxide following the reaction:
4HNO3 → 2H2O + 4NO2 + O2 (72 deg C)
which means that anhydrous nitric acid should be stored below 0 deg C to avoid decomposition. The nitrogen dioxide (NO2) remains dissolved in the nitric acid coloring it yellow, or red at higher temperatures.
3)用降氣壓(半真空)的方法,使nitrogen oxides自然排走。
The dissolved NOx are readily removed using reduced pressure at room temperature (10-30 min at 200 mmHg or 27 kPa). Obtained white fuming nitric acid has density 1.51 g/cm^3. This procedure can also be performed under reduced pressure and temperature in one step in order to produce less nitrogen dioxide gas.
希望解答到你 ^^


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