Salt bridge問題~

2007-09-24 3:00 am
有一個cell,一邊就用acidified potassium permanganate solution做electrolyte,
另一邊就用potassium iodide solution做electrolyte:中間加一條salt bridge soaked with
potassium nitrate solution .

問題:Explain whether a sodium sulphite solution can be used instead of
a potassium nitrate solution in the salt bridge.

答案:no,sodium sulphite solution can be oxidized by permanganate ion

點解NaSO3會比MnO4- oxidized?

如果兩邊改用MgSO4 and Zn(NO3)2, salt bridge soaked with NaCl,
咁點解 sodium chloride 唔會比 sulphate ion oxidized

回答 (2)

2007-09-24 9:57 pm
✔ 最佳答案
點解 Na2SO3 會比 MnO4- oxidize?
SO32- is a reducing agent, and MnO4- is an oxidizing agent
so they will undergo redox reaction
點解 sodium chloride 唔會比 sulphate ion oxidize?
SO42- is an oxidizing agent only when it is concentrated
參考: me*
2007-09-24 8:37 am
可以用Standard reduction potential 計下 個reaction 係咪feasible.
E=Ecathode-Eanode, ,如果E>0 ,個reaction 通常都feasible
[url]http://www.csudh.edu/oliver/chemdata/data-e.htm[/url]


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