✔ 最佳答案
Because sodium hydroxide NaOH react with carbon dioxide CO2 in the air to form sodium bicarbonate NaHCO3 and sodium carbonate Na2CO3
NaOH + CO2 -> NaHCO3
2NaOH + CO2 -> Na2CO3 + H2O
which decrease the alkaline value of the dilute hydroxide solution with time, so it is not a good primary standard.